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Molekula

Molekula

Triphenylphosphine (TPP) Crystals

SKU 90029850 CAS 603-35-0 (C6H5)3P MW 262.29 Made to order Bulk quantities on request

Supplying 4,500+ customers in over 80 countries

ISO 9001:2015 & ISO 14001:2015 certified · Supplying laboratories and industry since 2000 · Listed pack sizes are a starting point — we manufacture, source and repack to the quantity you need

Triphenylphosphine (TPP) Crystals is a white, crystalline organophosphorus compound widely used as a ligand in homogeneous catalysis, a reagent in organic synthesis, and a stabilizer in polymers. It is also employed as a stoichiometric reagent in Wittig reactions and as a precursor to quaternary phosphonium salts, which are used as phase-transfer catalysts. This high-purity chemical has a CAS number of 603-35-0, a molecular formula of (C6H5)3P, and a molecular weight of 262.29 g/mol. It must be stored at ambient conditions and handled with caution, as it carries a Danger signal word. Molekula supplies Triphenylphosphine Crystals from research to bulk quantities with full documentation and ISO 9001:2015 traceability.

Expect a response within hours Speak to a chemist: +44 (0) 3302 000333

Example image for illustration only. Other packaging and pack sizes are available.

Pricing & pack sizes

Pack sizes & pricing

Pricing on request — packs available from research to bulk quantities.

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Specifications

Property Value
Appearance White Crystals
Melting Point 80-82°C
Content (HPLC) >99.7
Iron (Fe) 9-10 ppm
Sulphates (SO4)(2-) 9-13 ppm
Chlorine (Cl) 11-13 ppm

Storage & handling

Property Value
Storage Temperature Ambient
Flash Point 180 °C
Acidity Neutral

Identification

Property Value
SKU 90029850
CAS Number 603-35-0
Molecular Formula (C6H5)3P
Molecular Weight 262.29
SMILES C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3
REACH Code Y110
TSCA Listed Yes
HTS Code 2931.49.00.80
Tariff Code 2931498090

Safety & GHS

Danger
  • GHS pictogram — Corrosive Corrosive GHS05
  • GHS pictogram — Health Hazard Health Hazard GHS07
  • GHS pictogram — Serious Health Hazard Serious Health Hazard GHS08

Hazard statements

  • H302+332 Harmful if swallowed or inhaled
  • H317 May cause an allergic skin reaction
  • H318 Causes serious eye damage
  • H372 Causes damage to organs through prolonged or repeated exposure
  • H373 May cause damage to organs through prolonged or repeated exposure
  • H412 Harmful to aquatic life with long lasting effects

Precautionary statements

  • P260 Do not breathe dust/fume/gas/mist/vapours/spray
  • P273 Avoid release to the environment
  • P280 Wear protective gloves/protective clothing/eye protection/face protection
  • P301+312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
  • P302+352 IF ON SKIN: Wash with soap and water
  • P305+351+338 IF IN EYES: Rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing

Documents

Safety Data Sheets (SDS)

Available in English, French, German, Italian, Spanish.

Certificate of Analysis (CoA) by batch

Enter a lot or batch number to retrieve the CoA for that specific batch. We can generate one from spec data if no PDF is on file.

Synonyms

No alternate names recorded for this product.

Frequently asked questions

What is triphenylphosphine (TPP) crystals commonly used for?

Triphenylphosphine is widely used as a ligand in homogeneous catalysis (e.g., palladium-catalyzed cross-coupling and rhodium-catalyzed hydroformylation), as a stoichiometric reagent in organic synthesis (e.g., Wittig, Mitsunobu, Appel and Staudinger reactions, where it is converted to triphenylphosphine oxide), and in the production of phosphonium salts and stabilizers.

What is the chemical formula and molecular weight of TPP?

The chemical formula is (C6H5)3P, and the molecular weight is 262.29 g/mol.

How should triphenylphosphine crystals be stored?

Store in a tightly sealed container at ambient temperature, away from moisture and oxidizing agents, in a well-ventilated area.

What grades of triphenylphosphine does Molekula supply?

Molekula supplies technical-grade and reagent-grade triphenylphosphine crystals, with purity typically ≥98% for reagent-grade applications.

Can Molekula supply triphenylphosphine in bulk quantities?

Yes, Molekula can supply bulk quantities of TPP crystals (typically ≥25 kg) upon request, subject to availability and customer-specific requirements.

What documentation comes with an order of triphenylphosphine?

Each order includes a Certificate of Analysis (CoA), Material Safety Data Sheet (MSDS), and a packing list; additional documentation like a Technical Data Sheet (TDS) or batch-specific records is available upon request.

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