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Molekula

Molekula

4-Hydroxybenzoic acid

SKU 34099106 CAS 99-96-7 HOC6H4CO2H MW 138.12 In stock (5+ packs) — same-day dispatch Bulk quantities on request

Supplying 4,500+ customers in over 80 countries

ISO 9001:2015 & ISO 14001:2015 certified · Supplying laboratories and industry since 2000 · Listed pack sizes are a starting point — we manufacture, source and repack to the quantity you need

4-Hydroxybenzoic acid is an aromatic carboxylic acid widely used as a precursor in the synthesis of pharmaceuticals, preservatives (e.g., parabens), and agrochemicals. It serves as a key intermediate in organic chemistry for producing esters, dyes, and UV absorbers. This white crystalline solid has a CAS number of 99-96-7, a molecular formula of HOC6H4CO2H, and a molecular weight of 138.12 g/mol. Store at ambient conditions, but handle with caution—it carries a **Danger** signal word due to potential health risks. Molekula supplies 4-hydroxybenzoic acid from research to bulk quantities with full documentation and ISO 9001:2015 traceability.

Expect a response within hours Speak to a chemist: +44 (0) 3302 000333

Example image for illustration only. Other packaging and pack sizes are available.

Pricing & pack sizes

Pack sizes & pricing

These pack sizes aren't a limit. Molekula manufactures, sources and repacks to order — if you need 500 kg and only see 1 kg listed, . We quote from grams to multi-tonne.

Need a different size? Add the nearest pack and change the size in your basket — we price it at the same rate per unit.

  • 100 g — £26.40 per pack ex VAT · £31.68 inc. VAT
  • 500 g — £59.20 per pack ex VAT · £71.04 inc. VAT

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Specifications

Property Value
Appearance White crystalline powder
Melting Point 214 - 217°C
Heavy metals ≤10ppm
Identification Conforms to reference
Loss on Drying ≤0.5%
Solubility Clear and Transparent
Residue on Ignition ≤0.5%
Purity (dry basis) ≥ 99%
Sulphates (SO4)(2-) ≤0.05%
Chlorine (Cl) ≤0.02%

Storage & handling

Property Value
Storage Temperature Ambient
Flash Point 199 °C
Acidity Acid

Literature values

Published physical properties of the substance, not batch specifications.

Property Value
Melting Point 214.5 °C
Boiling Point 334 to 335 °C at 760 mmHg
Density 1.46 g/cm³ at 25 °C
Water Solubility 5 g/L at 25 °C
Solubility (other solvents) Slightly soluble in water; soluble in organic solvents
Vapour Pressure 1.9 × 10⁻⁷ mmHg at 25 °C (Extrapolated)
pKa pKa = 4.54
log P (octanol/water) 1.58

Source: PubChem CID 135 (HSDB, Human Metabolome Database (HMDB), Joint FAO/WHO Expert Committee on Food Additives (JECFA))

Identification

Property Value
SKU 34099106
CAS Number 99-96-7
IUPAC Name 4-hydroxybenzoic acid
EC Number 202-804-9
Molecular Formula HOC6H4CO2H
Molecular Weight 138.12
Exact Mass 138.0317
SMILES C1=CC(=CC=C1C(=O)O)O
InChIKey FJKROLUGYXJWQN-UHFFFAOYSA-N
InChI InChI=1S/C7H6O3/c8-6-3-1-5(2-4-6)7(9)10/h1-4,8H,(H,9,10)
PubChem CID 135
REACH Code Y110
TSCA Listed Yes
HTS Code 29182965
Tariff Code 2918290090

Safety & GHS

Danger
  • GHS pictogram — Corrosive Corrosive GHS05
  • GHS pictogram — Health Hazard Health Hazard GHS07

Hazard statements

  • H318 Causes serious eye damage
  • H335 May cause respiratory irritation

Precautionary statements

  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray
  • P280 Wear protective gloves/protective clothing/eye protection/face protection
  • P305+351+338 IF IN EYES: Rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing
  • P308+313 IF exposed or concerned: Get medical advice/attention
  • P310 Immediately call a POISON CENTER or doctor/physician

Documents

Certificate of Analysis (CoA) by batch

Enter a lot or batch number to retrieve the CoA for that specific batch. We can generate one from spec data if no PDF is on file.

Synonyms

  • 4-Carboxyphenol
  • 4-Hydroxybenzoate
  • Benzoic acid, 4-hydroxy-
  • Benzoic acid, p-hydroxy-
  • FEMA NO. 3986
  • p-carboxyphenol
  • p-Hydroxybenzoic acid
  • p-Oxybenzoesaure
  • p-Salicylic acid
  • para-Hydroxybenzoic acid

Frequently asked questions

What is 4-Hydroxybenzoic acid commonly used for?

4-Hydroxybenzoic acid is primarily used as a precursor in the synthesis of parabens (preservatives), pharmaceuticals, and as a monomer in polymer production.

What is the chemical formula and molecular weight of 4-Hydroxybenzoic acid?

The chemical formula is **HOC₆H₄CO₂H** and the molecular weight is **138.12 g/mol**.

How should 4-Hydroxybenzoic acid be stored?

Store at **ambient temperature** in a cool, dry place, away from incompatible substances and moisture.

What grades of 4-Hydroxybenzoic acid does Molekula supply?

Molekula supplies **pharmaceutical (USP/EP), food-grade, and technical-grade** 4-Hydroxybenzoic acid, depending on application requirements.

Can Molekula supply 4-Hydroxybenzoic acid in bulk quantities?

Yes, Molekula can supply **bulk quantities** (from kilograms to metric tons) of 4-Hydroxybenzoic acid, with flexible packaging options.

What documentation comes with an order of 4-Hydroxybenzoic acid?

Each order includes a **Certificate of Analysis (CoA), Safety Data Sheet (SDS), and batch-specific documentation** for traceability and compliance.

Ready to order or need a custom pack?

Tell us the product, grade, and quantity — Molekula usually responds within one working day with pricing and lead time.

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