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Ethynylmagnesium Bromide, 0.5M in Tetrahydrofuran

CAS 4301-14-8 HC≡CMgBr MW 129.24 In stock

Ethynylmagnesium bromide, 0.5M in tetrahydrofuran, is a Grignard reagent used in organic synthesis for carbon-carbon bond formation, particularly in the preparation of alkynes and other functionalized compounds. It is supplied in a stable, anhydrous tetrahydrofuran solution. CAS: 4301-14-8, molecular formula: HC≡CMgBr, molecular weight: 129.24 g/mol, stored at 2 to 8 °C. Danger signal word applies due to flammability and reactivity. Molekula supplies Ethynylmagnesium Bromide from research to bulk quantities with full documentation and ISO 9001:2015 traceability.

CoA by batch

Overview

Ethynylmagnesium bromide, 0.5M in tetrahydrofuran, is a Grignard reagent used in organic synthesis for carbon-carbon bond formation, particularly in the preparation of alkynes and other functionalized compounds. It is supplied in a stable, anhydrous tetrahydrofuran solution. CAS: 4301-14-8, molecular formula: HC≡CMgBr, molecular weight: 129.24 g/mol, stored at 2 to 8 °C. Danger signal word applies due to flammability and reactivity. Molekula supplies Ethynylmagnesium Bromide from research to bulk quantities with full documentation and ISO 9001:2015 traceability.

Pricing & pack sizes

Pack sizes & pricing

  • 100 mL £59.20 per pack

Prices exclude VAT/sales tax and shipping. Bulk and custom pack sizes available on request.

Specifications

Property Value
Appearance Clear to hazy, colourless to yellow to grey to brown liquid
Assay (Titration) 0.40-0.60M
Note May develop some turbidity or precipitate

Storage & handling

Property Value
Storage Temperature 2 to 8 °C
Flash Point -17 C
Transport Class 4.3 (3)
Packing Group II
Shelf Life 12 months
Acidity Base

Identification

Property Value
CAS Number 4301-14-8
Molecular Formula HC≡CMgBr
Molecular Weight 129.24
SMILES C#[C-].[Mg+2].[Br-]
EC / UN Number 3399
REACH Code Y110
HTS Code 2931.90.9052
Tariff Code 2931900090

Safety & GHS

Danger
  • GHS pictogram — Flammable Flammable GHS02
  • GHS pictogram — Corrosive Corrosive GHS05
  • GHS pictogram — Health Hazard Health Hazard GHS07
  • GHS pictogram — Serious Health Hazard Serious Health Hazard GHS08

Hazard statements

  • EUH014 Reacts violently with water
  • EUH019 May form explosive peroxides
  • H225 Highly flammable liquid and vapour
  • H261 In contact with water releases flammable gas
  • H314 (sub cat. 1B) Causes severe skin burns and eye damage
  • H336 May cause drowsiness or dizziness
  • H351 Suspected of causing cancer

Precautionary statements

  • P210 Keep away from heat/sparks/open flames/hot surfaces - No smoking
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray
  • P280 Wear protective gloves/protective clothing/eye protection/face protection
  • P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
  • P303+361 IF ON SKIN (or hair): Remove immediately all contaminated clothing. Rinse with water/shower
  • P305+351+338 IF IN EYES: Rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing
  • P308+313 IF exposed or concerned: Get medical advice/attention

For research and industrial use only

Not for use in food, drugs, household, or in or on humans or animals. Consult the Safety Data Sheet before handling.

Documents

Certificate of Analysis (CoA) by batch

Enter a lot or batch number to retrieve the CoA for that specific batch. We can generate one from spec data if no PDF is on file.

Synonyms

No alternate names recorded for this product.

Frequently asked questions

What is Ethynylmagnesium Bromide used for?

It is primarily used as a nucleophilic reagent in organic synthesis, particularly for forming carbon-carbon bonds in the preparation of alkynes and other complex molecules.

What is the chemical formula and molecular weight?

The formula is HC≡CMgBr with a molecular weight of 129.24 g/mol.

How should Ethynylmagnesium Bromide be stored?

It must be stored at 2 to 8 °C and protected from moisture and air to maintain stability.

What grade is available for this product?

This product is available as a standard reagent grade, suitable for laboratory-scale synthetic applications.

Can Molekula supply Ethynylmagnesium Bromide in bulk?

Yes, Molekula can supply this reagent in bulk quantities—please contact our sales team for custom order details.

What documentation comes with the order?

Each order includes a Certificate of Analysis (CoA) and Safety Data Sheet (SDS) with the shipment.

Ready to order or need a custom pack?

Tell us the product, grade, and quantity — Molekula usually responds within one working day with pricing and lead time.

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